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Science of Interfacial Phenomena

vivanite surface structure
Vivanite surface structure

Fundamental understanding of the physical and chemical properties of interfaces in natural and engineered materials is a critical component of environmental and energy-related research, understanding and controlling global warming, and the development of technologies important to the mission of DOE and society. The importance of interfaces has been highlighted in DOE science workshops on topics that include geosciences, solid-state lighting, solar energy, and advanced nuclear energy systems.

Tailored or designed surfaces and interfaces are important as model systems for detailed study of processes that occur on natural heterogeneous materials present in atmospheric or subsurface environments and for developing materials with new properties for
energy production, catalysis, and numerous other applications.

The behaviors of complex heterogeneous materials in the environment (such as aerosol photochemistry or contaminant migration) will never be fully understood without model systems that allow specific aspects of that complexity to be examined in detail. Likewise, material systems with interfaces optimized with specific properties are essential for developing technologies needed for a stable environment and a secure energy future. Understanding complex interfaces requires methods to characterize naturally complex materials and minerals found in the environment and to understand increasingly complex materials designed and synthesized for a desired functionality. These science issues complement and naturally intersect those of the biological and geoscience science themes.

Two of the significant scientific challenges related to advancing interfacial science are: 1) developing (and verifying) predictive models for interfacial processes with energy and environmental implications, and 2) advancing the understanding of structure-function relationships in complex multi-component interfacial systems. The Science of Interfacial Phenomena science theme is focused on research activities that address these two scientific challenges in specific areas with high environmental or energy impact, such as:

Fields and technologies that will be impacted by the improved understanding and control of molecular-level structural, dynamic, and transport properties of interfaces include the following:

Research capabilities and expertise at EMSL enable the design and characterization of a variety of material systems with specialized atomic, electronic, and ionic transport and interfacial properties. EMSL's unique blend of capabilities and staff expertise makes it a premier laboratory for the study of oxide materials and mineral surfaces.

  1. Low-cost and durable catalyst support for fuel cells: graphite submicronparticles.
  2. Fluorescent Dye Encapsulated ZnO Particles with Cell-specific Toxicity for Potential use in Biomedical Applications.
  3. The Oil-Water Interface: Mapping the Solvation Potential.
  4. Nanotechnology-Based Electrochemical Sensors for Biomonitoring Chemical Exposures .
  5. Anisotropy of disorder accumulation and recovery in 6H-SiC irradiated with Au2+ ions at 140 K.
  1. Microstructures of ZnO Films Deposited on (0001) and r-cut α-Al2O3 Using Metal Organic Chemical Vapor Deposition (Sapphires & Sunscreen)
  2. A Fast Analysis Technique to Evaluate Scintillation Response (Let There Be Light Yield)
  3. Probing Reaction Pathways Using in situ 1H NMR Spectroscopy (Hydrogen Does the Two Step)
  4. Conductivity of Oriented Samaria-Doped Ceria Thin Films Grown by Oxygen-Plasma-Assisted Molecular Beam Epitaxy (The Good Samaria)

Science of Interfacial Phenomena Capabilities Available at EMSL

Instrument Contact
Analytical: Chromatograph: Ion Wietsma, Tom
Analytical: Inductively Coupled Plasma-Mass Spec (ICP-MS) Wietsma, Tom
Analytical: Total Organic Carbon Analyzer (TOC) Wietsma, Tom
Analytical: Chromatograph: Gas/Mass Spec System 2005 Wietsma, Tom
Analytical: Chromatograph: Liquid Wietsma, Tom
Atmospheric Pressure Reactor System Tonkyn, Russell
Catalysis: UHV Model Catalysts, High Pressure Szanyi, Janos
Computing: Chinook (HP 2310-Node Linux Cluster) Vorpagel, Erich
Computing: Data File Storage (NWfs) Cowley, David E
Wright, Ryan
Computing: NW-ICE
Computing: SGI 16-processor Graphics Server (nwvisus) Vorpagel, Erich
Computing: Spokane Cluster Bylaska, Eric
Rosso, Kevin M.
Deposition: Molecular Beam Epitaxy #1 Chambers, Scott
Droubay, Timothy C
Kaspar, Tiffany C
Deposition: Molecular Beam Epitaxy #2 Thevuthasan, Theva
Deposition: Pulsed Laser Deposition System Chambers, Scott
Droubay, Timothy C
Kaspar, Tiffany C
Electron and Photon Stimulated Desorption (BES 2) Kimmel, Greg
Electron Microscope: Transmission, High Resolution Wang, Chongmin
Electron Microscope: Dual FIB/SEM Arey, Bruce
Saraf, Lax
Electron Microscope: Transmission, CRYO 2005 Dohnalkova, Alice
Electron Spectrometer: Auger/Scanning Auger Lea, Scott
Electron Spectrometer: HREELS, UHV Surface Chemistry Henderson, Mike
Electron Spectrometer: Scanning Multiprobe Surface Analysis System - Versaprobe Nachimuthu, Ponnusamy
Electron Spectrometer: XPS High Resolution (Quantum) Engelhard, Mark
Energetic Processes (Surfaces/Solids) Instrumentation w/Lasers Beck, Kenneth M.
Hess, Wayne P
EPR Spectrometer Pulsed/CW (X-band, 9.5 GHz) Amonette, Jim
Hoyt, David W
Walter, Eric
Ion Accelerator, Beam Lines, and End Stations Shutthanandan, Shuttha
Liquid-Beam Source Kimmel, Greg
Petrik, Nikolay
Mass Spectrometer: FT-ICR 6 T (Ion Surface Collisions) Laskin, Julia
Mass Spectrometer: Isotope Ratio Alexander, M Lizabeth
Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) - 2007 Thevuthasan, Theva
Zhu, Zihua
Mass-Selected Ion Deposition System - Electrospray Source Laskin, Julia
Microfabrication Laboratory (Clean Room) 1302 Saraf, Lax
Microscope: Photoemission Electron (PEEM) Beck, Kenneth M.
Microscope: Scanning Probe - AFM, Bioscope Rosso, Kevin M.
Microscope: Scanning Probe - STM/AFM, PicoSPM Rosso, Kevin M.
Microscope: Scanning Probe, DI Nanoscope IIIa Multimode Lea, Scott
Microscope: Scanning Probe, Variable Temperature Lyubinetsky, Igor
Microscope: Scanning Probe, Variable Temperature UHV Dohnalek, Zdenek
Molecular Beam Kinetics Smith, Scott
NMR Spectrometer: 2 Tesla Horizontal Bore Varian (Imaging) Ford,Joseph J
Minard, Kevin R
NMR Spectrometer: 300 MHz WB Tecmag Discovery (radioactive samples) Burton, Sarah D
Cho, Herman M
NMR Spectrometer: 300 MHz WB Varian (Solids) Burton, Sarah D
NMR Spectrometer: 500 MHz WB Bruker (Imaging) Majors, Paul D.
NMR Spectrometer: 500 MHz WB Varian (Solids) Burton, Sarah D
Lipton, Andrew S
NMR Spectrometer: 750 MHz NB (17.6 Tesla) Varian Burton, Sarah D
Hoyt, David W
Isern, Nancy
NMR Spectrometer: 800 MHz (18.8 Tesla) Varian Cryoprobe (Liquids) Hoyt, David W
Isern, Nancy
NMR Spectrometer: 900 MHz (21.1 Tesla) Varian Burton, Sarah D
Hoyt, David W
Lipton, Andrew S
Photoelectron Spectroscopy - Low Temperature Joly, Alan G
Spectrometer: Fluorimeter Wang, Zheming
Spectrometer: Mossbauer Kukkadapu, Ravi
Spectrometer: Fluorescence, Cryogenic Wang, Zheming
Spectrometer: Fluorescence, Picosecond Joly, Alan G
Spectrometer: FTIR - standard Johnson, Tim
Spectrometer: Raman, Confocal Hess, Nancy J.
Spectrometer: Sum Frequency/Second Harmonic Generation, Picosecond, Surface Spectroscopy - (avail. Nov. 2010) Joly, Alan G
Wang, Hongfei
Spectroscopy: Fluorescence, Time-resolved Wang, Zheming
Surface Dynamics/Ion Deposition System Cowin, Jim
Iedema, Martin
Transient Kinetic Analysis (TKA) Szanyi, Janos
X-ray Diffraction: Four-Circle Bowden, Mark
Varga, Tamas
X-ray Diffraction: General Purpose Bowden, Mark
Varga, Tamas
X-ray Diffraction: Microbeam Bowden, Mark
Varga, Tamas
X-ray Diffraction: Single Crystal Bowden, Mark
Varga, Tamas
X-ray Diffraction: Special Applications Bowden, Mark
Varga, Tamas